Organometallic chemistry: synthesis and applications of cyclometallated compounds
Mass, IR and NMR spectra of selected compounds
Cyclometallated compounds
benzylamine
trans-N,N-[Pd(C6H4CH2NH2)(OAc)(py-d5)].
1H (300 MHz, CDCl3,
SiMe4, 298 K).
trans-N,N-[Pd(3-DC6H3CH2NH2)(OAc)(py-d5)].
1H (300 MHz, CDCl3,
SiMe4, 298 K).
trans-N,P-[Pd(C6H4CH2NH2)(Cl)(PPh3)].
FAB
(+) (Cs, 10 kV, 2-nitrobenzyl alcohol).
IR (KBr, 4000-400 cm-1). 1H
(200 MHz, CDCl3, SiMe4,
298 K). 31P{1H} (101.26 MHz, CHCl3, P(OMe)3,
298K).
benzyl-benzylidene-amine
trans-(m-OAc)2[Pd(C6H4CH=NCH2C6H5)]2.
1H (200 MHz, CDCl3,
SiMe4, 298 K).
trans-N,N-[Pd(C6H4CH=NCH2C6H5)(OAc)(py-d5)].
1H (300 MHz, CDCl3,
SiMe4, 298 K).
trans-N,P-[Pd(C6H4CH=NCH2C6H5)(OAc)(PPh3)].
IR
(KBr, 4000-400 cm-1). 1H
(200 MHz, CDCl3, SiMe4,
298 K). 31P{1H} (101.26 MHz, CHCl3, P(OMe)3,
298K).
[Pd(C6H4CH=NCH2C6H5)(acac)].
1H (200 MHz, CDCl3,
SiMe4, 298 K).
2-phenylaniline
(m-Cl)2[Pd{NH2C6H4(C6H4)}]2.
IR (KBr, 4000-400 cm-1).
trans-N,P-[Pd{NH2C6H4(C6H4)}Cl(PPh3)].
31P{1H} (101.26
MHz, CHCl3, P(OMe)3, 298K).